If you choose the model in the manner your described, you'll get a linear regression model (linear in parameters, not in the X's). So if you want to have non-linear (e. g. quadratic) X's you have to calculate a new variable with X²-values and make another regression with X² instead of X.
Developing a linear regression model includes a few steps:
1. Make a scatterplot matrix of all X vs. Y to detect the kind of dependencies. If you see a non-linear connection, transform X in a manner that the connection is afterwards (nearly) linear. (Nice candidates to start are log(x), 1/x, x², x³,..)
2. Let the software build your model and take a deep look at the residual plots! Minitab gives you four: qq-plot, residuals vs. fitted, histogram and a run chart. The values should all be near the line in the qq-plot. There shouldn't be a pattern at the residuals vs. fitted plot, the histogram should be bell-shaped and the run chart shouldn't have patterns either.
3. If patterns exist: Go back to the process (or the source of data) and look for systematic influences, perhaps there are factors which were forgotten to track. If there are time-dependencies, a time-series model could be more appropriate than a simple linear regression model. If you have a heteroscedastic residuals vs. fitted plot (looks like a trumpet), the variance of the response Y is not constant. You have to find a transformation for Y there.
4. If patterns are absent: R² should be "good enough" (for production higher than .80). If the linear model is appropriate and despite this R² is poor, the variation among the X's is too high.
To answer your first question: The default is that all X's are modeled linear. A search for better modelling as a standard procedure will perhaps give you the best fitted model from a mathematical viewpoint, but it will be more difficult to interpret it and it could be an over-fitted model. E. g. for 8 X's and the number of possible transformations restricted to 6 the software has to build 6^8=1'679'616 different models and select the best one.
Regards,
Barbara