You have some flexibility here as long as it is clear.
While you didn't answer the other questions, I cover the different scenarios and how I would handle them. If the material is held pending the acceptable results of this off-line test, I would include it in the product control methods section for that operation and note that it is an off-line test. If it is simply a process monitoring test (not a product acceptance test), and material continues to flow through the process while the test is performed, I would show it in the process monitoring methods section. You can show it as a separate operation as long as you are clear and the people responsible understand their roles. Ultimately, its about the effectiveness of the control plan.