MSDS is not a "static" document; it is dynamic for quite a few substances. As more and more information becomes available they get added to the MSDS. One of the major points that I always check is the TLV (or an equivalent National standard like MAC..values vary from country to country in quite a few cases)- at least I have seen the TLV (TWA) values changing for trichloroethylene, mercury etc., in the last twenty years. Another case in point is CFCs (Ozone depletion..disposal aspects). If one is maintaining an ISO-14001, I would suggest a review of the MSDS relevant to the organization at least once a year (one can, then, be ahead of legislation with respect to issues arising out of theses substances). No doubt, most of the times one would not add any new data to the MSDS. But to ensure that there has been no change in the data (or identifying a change well in advance) is an aspect of risk reduction covered under ISO-14001 (or any other appropriate management system).
Ramakrishnan